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Phases of ice and water The normal form of ice on the surface of Earth is Ice Ih, a phase that forms crystals with hexagonal symmetry. Another with cubic crystalline symmetry, Ice Ic, can occur in the upper atmosphere.[36] As the pressure increases, ice forms other crystal structures. As of 2019, 17 have been experimentally confirmed and several more are predicted theoretically.[37] When sandwiched between layers of graphene, ice forms a square lattice.[38] The details of the chemical nature of liquid water are not well understood; some theories suggest that its unusual behaviour is due to the existence of 2 liquid states.[15][39][40][41] Taste and odor Pure water is usually described as tasteless and odorless, although humans have specific sensors that can feel the presence of water in their mouths,[42] and frogs are known to be able to smell it.[43] However, water from ordinary sources (including bottled mineral water) usually has many dissolved substances, that may give it varying tastes and odors. Humans and other animals have developed senses that enable them to evaluate the potability of water by avoiding water that is too salty or putrid.[44] Color and appearance Main article: color of water See also: electromagnetic absorption by water Pure water is visibly blue due to absorption of light in the region ca. 600 nm - 800 nm.[45] The color can be easily observed in a glass of tap-water placed against a pure white background, in daylight.The principal absorption bands bands responsible for the color are overtones of the O-H stretching vibrations. The apparent intensity of the color increases with the depth of the water column, following Beer's law. This also applies, for example, with a swimming pool when the light source is sunlight reflected from the pool's white tiles. In nature, the color may also be modified from blue to green due to the presence of suspended solids or algae. In industry, near-infrared spectroscopy is used with aqueous solutions as the greater intensity of the lower overtones of water means that glass cuvettes with short path-length may be employed. To observe the fundamental stretching absorption spectrum of water or of an aqueous solution in the region around 3500 cm-1 (2.85 m)[46] a path length of about 25 m is needed. Also, the cuvette must be both transparent around 3500 cm-1 and insoluble in water; calcium fluoride is one material that is in common use for the cuvette windows with aqueous solutions. The Raman-active fundamental vibrations may be observed with, for example, a 1 cm sample cell. Aquatic plants, algae, and other photosynthetic organisms can live in water up to hundreds of meters deep, because sunlight can reach them. Practically no sunlight reaches the parts of the oceans below 1,000 meters (3,300 ft) of depth. The refractive index of liquid water (1.333 at 20 C (68 F)) is much higher than that of air (1.0), similar to those of alkanes and ethanol, but lower than those of glycerol (1.473), benzene (1.501), carbon disulfide (1.627), and common types of glass (1.4 to 1.6). The refraction index of ice (1.31) is lower than that of liquid water. Polar molecule Tetrahedral structure of water In a water molecule, the hydrogen atoms form a 104.5 angle with the oxygen atom. The hydrogen atoms are close to two corners of a tetrahedron centered on the oxygen. At the other two corners are lone pairs of valence electrons that do not participate in the bonding. In a perfect tetrahedron, the atoms would form a 109.5 angle, but the repulsion between the lone pairs is greater than the repulsion between the hydrogen atoms.[47][48] Other substances have a tetrahedral molecular structure, for example, methane (CH 4) and hydrogen sulfide (H 2S). However, oxygen is more electronegative (holds on to its electrons more tightly) than most other elements, so the oxygen atom retains a negative charge while the hydrogen atoms are positively charged. Along with the bent structure, this gives the molecule an electrical dipole moment and it is classified as a polar molecule.[49] Water is a good polar solvent, that dissolves many salts and hydrophilic organic molecules such as sugars and simple alcohols such as ethanol. Water also dissolves many gases, such as oxygen and carbon dioxidethe latter giving the fizz of carbonated beverages, sparkling wines and beers. In addition, many substances in living organisms, such as proteins, DNA and polysaccharides, are dissolved in water. The interactions between water and the subunits of these biomacromolecules shape protein folding, DNA base pairing, and other phenomena crucial to life (hydrophobic effect). Many organic substances (such as fats and oils and alkanes) are hydrophobic, that is, insoluble in water. Many inorganic substances are insoluble too, including most metal oxides, sulfides, and silicates. Hydrogen bonding See also: Chemical bonding of water Model of hydrogen bonds (1) between molecules of water. Because of its polarity, a molecule of water in the liquid or solid state can form up to four hydrogen bonds with neighboring molecules. Hydrogen bonds are about ten times as strong as the Van der Waals force that attracts molecules to each other in most liquids. This is the reason why the melting and boiling points of water are much higher than those of other analogous compounds like hydrogen sulfide. They also explain its exceptionally high specific heat capacity (about 4.2 J/g/K), heat of fusion (about 333 J/g), heat of vaporization (2257 J/g), and thermal conductivity (between 0.561 and 0.679 W/m/K). These properties make water more effective at moderating Earth's climate, by storing heat and transporting it between the oceans and the atmosphere. The hydrogen bonds of water are around 23 kJ/mol (compared to a covalent O-H bond at 492 kJ/mol). Of this, it is estimated that 90% is attributable to electrostatics, while the remaining 10% is partially covalent.[50] These bonds are the cause of water's high surface tension[51] and capillary forces. The capillary action refers to the tendency of water to move up a narrow tube against the force of gravity. This property is relied upon by all vascular plants, such as trees.[52] Self-ionisation Main article: Self-ionisation of water Water is a weak solution of hydronium hydroxide - there is an equilibrium 2H 2O ? H 3O+ + OH- , in combination with solvation of the resulting hydronium ions. Electrical conductivity and electrolysis Pure water has a low electrical conductivity, which increases with the dissolution of a small amount of ionic material such as common salt. Liquid water can be split into the elements hydrogen and oxygen by passing an electric current through ita process called electrolysis. The decomposition requires more energy input than the heat released by the inverse process (285.8 kJ/mol, or 15.9 MJ/kg).[53] Mechanical properties Liquid water can be assumed to be incompressible for most purposes: its compressibility ranges from 4.4 to 5.110-10 Pa-1 in ordinary conditions.[54] Even in oceans at 4 km depth, where the pressure is 400 atm, water suffers only a 1.8% decrease in volume.[55] The viscosity of water is about 10-3 Pas or 0.01 poise at 20 C (68 F), and the speed of sound in liquid water ranges between 1,400 and 1,540 meters per second (4,600 and 5,100 ft/s) depending on temperature. Sound travels long distances in water with little attenuation, especially at low frequencies (roughly 0.03 dB/km for 1 kHz), a property that is exploited by cetaceans and humans for communication and environment sensing (sonar).[56] Reactivity Metallic elements which are more electropositive than hydrogen, particularly the alkali metals and alkaline earth metals such as lithium, sodium, calcium, potassium and cesium displace hydrogen from water, forming hydroxides and releasing hydrogen. At high temperatures, carbon reacts with steam to form carbon monoxide and hydrogen. On Earth Main articles: Hydrology and Water distribution on Earth Water covers 71% of the Earth's surface; the oceans contain 96.5% of the Earth's water. The Antarctic ice sheet, which contains 61% of all fresh water on Earth, is visible at the bottom. Condensed atmospheric water can be seen as clouds, contributing to the Earth's albedo. Hydrology is the study of the movement, distribution, and quality of water throughout the Earth. The study of the distribution of water is hydrography. The study of the distribution and movement of groundwater is hydrogeology, of glaciers is glaciology, of inland waters is limnology and distribution of oceans is oceanography. Ecological processes with hydrology are in focus of ecohydrology. The collective mass of water found on, under, and over the surface of a planet is called the hydrosphere. Earth's approximate water volume (the total water supply of the world) is 1.386 109 cubic kilometers (3.33 108 cubic miles).[2] Liquid water is found in bodies of water, such as an ocean, sea, lake, river, stream, canal, pond, or puddle. The majority of water on Earth is sea water. Water is also present in the atmosphere in solid, liquid, and vapor states. It also exists as groundwater in aquifers. Water is important in many geological processes. Groundwater is present in most rocks, and the pressure of this groundwater affects patterns of faulting. Water in the mantle is responsible for the melt that produces volcanoes at subduction zones. On the surface of the Earth, water is important in both chemical and physical weathering processes. Water, and to a lesser but still significant extent, ice, are also responsible for a large amount of sediment transport that occurs on the surface of the earth. Deposition of transported sediment forms many types of sedimentary rocks, which make up the geologic record of Earth history. Water cycle Main article: Water cycle Water cycle The water cycle (known scientifically as the hydrologic cycle) refers to the continuous exchange of water within the hydrosphere, between the atmosphere, soil water, surface water, groundwater, and plants. Water moves perpetually through each of these regions in the water cycle consisting of the following transfer processes: evaporation from oceans and other water bodies into the air and transpiration from land plants and animals into the air. precipitation, from water vapor condensing from the air and falling to the earth or ocean. runoff from the land usually reaching the sea. Most water vapor over the oceans returns to the oceans, but winds carry water vapor over land at the same rate as runoff into the sea, about 47 Tt per year. Over land, evaporation and transpiration contribute another 72 Tt per year. Precipitation, at a rate of 119 Tt per year over land, has several forms: most commonly rain, snow, and hail, with some contribution from fog and dew.[57] Dew is small drops of water that are condensed when a high density of water vapor meets a cool surface. Dew usually forms in the morning when the temperature is the lowest, just before sunrise and when the temperature of the earth's surface starts to increase.[58] Condensed water in the air may also refract sunlight to produce rainbows. Water runoff often collects over watersheds flowing into rivers. A mathematical model used to simulate river or stream flow and calculate water quality parameters is a hydrological transport model. Some water is diverted to irrigation for agriculture. Rivers and seas offer opportunity for travel and commerce. Through erosion, runoff shapes the environment creating river valleys and deltas which provide rich soil and level ground for the establishment of population centers. A flood occurs when an area of land, usually low-lying, is covered with water. It is when a river overflows its banks or flood comes from the sea. A drought is an extended period of months or years when a region notes a deficiency in its water supply. This occurs when a region receives consistently below average precipitation. Fresh water storage Main article: Water resources Water occurs as both "stocks" and "flows." Water can be stored as lakes, water vapor, groundwater or "aquifers," and ice and snow. Of the total volume of global freshwater, an estimated 69 percent is stored in glaciers and permanent snow cover; 30 percent is in groundwater; and the remaining 1 percent in lakes, rivers, the atmosphere, and biota.[59] The length of time water remains in storage is highly variable: some aquifers consist of water stored over thousands of years but lake volumes may fluctuate on a seasonal basis, decreasing during dry periods and increasing during wet ones. A substantial fraction of the water supply for some regions consists of water extracted from water stored in stocks, and when withdrawals exceed recharge, stocks decrease. By some estimates, as much as 30 percent of total water used for irrigation comes from unsustainable withdrawals of groundwater, causing groundwater depletion.[60] Sea water and tides Main articles: Seawater and Tides Sea water contains about 3.5% sodium chloride on average, plus smaller amounts of other substances. The physical properties of sea water differ from fresh water in some important respects. It freezes at a lower temperature


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